Magmatic carbon in Martian meteorites: attempts to constrain the carbon cycle on Mars

One of the current goals of Martian exploration is to find evidence for extinct (or even extant) life. Carbon (an essential ingredient of life on Earth) is known to occur on Mars as CO2 in the atmosphere and frozen in the polar caps; it is inferred to be present as carbonates in the Martian crust and soils. We are attempting to define and quantify the different carbon reservoirs on Mars, so that we can follow Mars’ carbon cycle. This paper discusses a primordial magmatic component that could be the starting point of such a cycle. The nature, distribution and isotopic composition of carbon was measured in a suite of Martian meteorites, comprising Chassigny and 11 shergottites. Other Martian meteorites were not included, as they sample rocks that have been altered by fluids at Mars’ surface. Our results, obtained by high-resolution stepped combustion and mass spectrometry, show that the magmatic component has a very variable abundance of 1–100 ppm, with d13Cyx20¡4ø. This value is close to magmatic carbon determined for Moon and for Vesta (the parent body of the HED basaltic meteorites), but very different from that of Earth. Received 13 July 2004, accepted 25 August 2004